Just a few day befor, one friend ask me some question about the product inventory, when will substrat the qty when place the order.
1.4 and above
<checkout_submit_all_after>
<observers>
<inventory>
<class>cataloginventory/observer</class>
<method>checkoutAllSubmitAfter</method>
</inventory>
</observers>
</checkout_submit_all_after>
1.3.4
<sales_order_item_save_before>
<observers>
<inventory>
<type>singleton</type>
<class>cataloginventory/observer</class>
<method>createOrderItem</method>
</inventory>
</observers>
</sales_order_item_save_before>